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1 article(s) from Liu, Si-Yuan

Water-soluble host–guest complexes between fullerenes and a sugar-functionalized tribenzotriquinacene assembling to microspheres

Si-Yuan Liu,
Xin-Rui Wang,
Man-Ping Li,
Wen-Rong Xu and
Dietmar Kuck

Beilstein J. Org. Chem. 2020, 16, 2551–2561, doi:10.3762/bjoc.16.207

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Graphical Abstract

Figure 1: Selected TBTQ derivatives 1–5 that bind fullerenes in host–guest complexes.

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Scheme 1: Synthetic route to TBTQ-(OG)₆.

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Figure 2: Fluorescence spectra of TBTQ-(OG)₆ (5.0 × 10⁻⁶ M) with varying concentrations of (a) C₆₀ and (b) C₇₀...

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Figure 3: Absorption spectra of (a) TBTQ-(OG)₆ [Graphic 2] C₆₀ [TBTQ-(OG)₆: 50 μM; C₆₀: 50 μM] and (b) TBTQ-(OG)₆ C₇₀ [...

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Figure 4: Absorption spectra of (a) TBTQ-(OG)₆ [Graphic 2] C₆₀ [TBTQ-(OG)₆: 50 μM; C₆₀: 50 μM] and (b) TBTQ-(OG)₆ C₇₀ [...

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Figure 5: Raman spectra of TBTQ-G₆, C₆₀ and TBTQ-G₆ [Graphic 2] C₆₀. Sample solutions of TBTQ-(OG)₆ (50 μM) and TBTQ-(OG)...

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Figure 6: Molecular model of the complex TBTQ-(OG)₆ [Graphic 2] C₆₀ in water, as generated by DFT calculations. (a) Side...

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Figure 7: SEM images of (a) C₆₀; (b) TBTQ-(OG)₆; (c) and (d) TBTQ-(OG)₆ [Graphic 2] C₆₀ (C₆₀: 1.4 mM; TBTQ-(OG)₆: 1.4 mM...

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Published 14 Oct 2020

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